全文获取类型
收费全文 | 2553篇 |
免费 | 71篇 |
国内免费 | 54篇 |
专业分类
化学 | 251篇 |
晶体学 | 2篇 |
力学 | 318篇 |
综合类 | 1篇 |
数学 | 1711篇 |
物理学 | 395篇 |
出版年
2023年 | 31篇 |
2022年 | 31篇 |
2021年 | 39篇 |
2020年 | 65篇 |
2019年 | 67篇 |
2018年 | 60篇 |
2017年 | 63篇 |
2016年 | 66篇 |
2015年 | 59篇 |
2014年 | 106篇 |
2013年 | 176篇 |
2012年 | 75篇 |
2011年 | 161篇 |
2010年 | 116篇 |
2009年 | 158篇 |
2008年 | 165篇 |
2007年 | 171篇 |
2006年 | 113篇 |
2005年 | 96篇 |
2004年 | 83篇 |
2003年 | 78篇 |
2002年 | 47篇 |
2001年 | 57篇 |
2000年 | 52篇 |
1999年 | 62篇 |
1998年 | 46篇 |
1997年 | 34篇 |
1996年 | 27篇 |
1995年 | 34篇 |
1994年 | 32篇 |
1993年 | 23篇 |
1992年 | 18篇 |
1991年 | 20篇 |
1990年 | 27篇 |
1989年 | 17篇 |
1988年 | 22篇 |
1987年 | 19篇 |
1986年 | 25篇 |
1985年 | 20篇 |
1984年 | 14篇 |
1983年 | 3篇 |
1982年 | 13篇 |
1981年 | 14篇 |
1980年 | 13篇 |
1979年 | 16篇 |
1978年 | 6篇 |
1977年 | 9篇 |
1976年 | 19篇 |
1974年 | 6篇 |
1966年 | 1篇 |
排序方式: 共有2678条查询结果,搜索用时 453 毫秒
31.
V. N. Manuilov T. Idehara M. Kamada T. Hayashi La Agusu T. Kanemaki K. Yatsui Wiehua Jiang 《International Journal of Infrared and Millimeter Waves》2006,27(9):1183-1193
High power Large Orbit Gyrotron (LOG) [1] is now under development at FIR FU. First version of this device was recently manufactured
and then assembled with power supply ETIGO-IV [2]. Results of preliminary tests of electron-optic system are presented. The
conditions when stableflat form of current pulse realized are discussed. Analytical estimations of cathode-anode distance
to achieve small influence of cathode plasma during high voltage (HV) pulse are performed.
Two new electron gun versions with decreased influence of the cathode plasma on its impedance and pulse form are suggested
and optimized. New optimal magnetic field distributions are found. First gun has quiasi-flat cathode configuration near the
anode diaphragm and provides operating current about 60 A. Second one uses blade cathode with operating current about 30 A.
Beam quality for both guns is suitable for LOG operation. 相似文献
32.
Peter Friz Nicolas Victoir 《Annales de l'Institut Henri Poincaré (B) Probabilités et Statistiques》2007,43(6):775-785
We study large deviation principles for Gaussian processes lifted to the free nilpotent group of step N. We apply this to a large class of Gaussian processes lifted to geometric rough paths. A large deviation principle for enhanced (fractional) Brownian motion, in Hölder- or modulus topology, appears as special case. 相似文献
33.
A recursive method is developed for the solution of coupled algebraic Riccati equations and corresponding linear Nash strategies of weakly interconnected systems. It is shown that the given algorithm converges to the exact solution with the rate of convergence ofO(2), where is a small coupling parameter. In addition, only low-order systems are involved in algebrdic computations; the amount of computations required does not grow per iteration and no analyticity assumption is imposed on the system coefficients.This work was supported by Rutgers University Research Council under Grant No. 2-02188. 相似文献
34.
35.
J. Lewin 《Journal of Optimization Theory and Applications》1986,49(3):411-430
A pursuerP, whose speed is bounded by 1, wants to get closer to an evaderE, whose speed is bounded by >1.P wants to reduce his distancePE fromE below the capture radius . Both players are confined to a circular arena. This problem is equivalent to a problem discussed by Flynn, who characterized and gave numerical bounds to the least upper boundd* on the values ofPE thatE can maintain. He used direct methods and did not use Isaacs' theory.We solve our problem relying on the theory of singular surfaces in differential games. We construct and investigate barriers of the game of kind, and we replace Flynn's bounds ond* by analytical (exact) values for various speeds .The support of the TW Department of THT, Enschede, Holland, is gratefully acknowledged. 相似文献
36.
High nuclearity paramagnetic, spin-coupled transition metal clusters and grids are fascinating chemists and physicists partly because of their structural beauty, and the challenge of creating them, but also because of their novel physical properties. Magnetic interactions between the spin centers are a primary focus. This review will examine a selection of Mn(II) polynuclear grids and clusters, with nuclearities in the range Mn4 to Mn9. Theoretical treatments of the magnetic properties are discussed, and approaches to solving the exchange problem for ‘large’ spin systems related to computational difficulties. A freely available software package (MAGMUN4.1) is presented as a means of dealing simply with spin-coupled clusters in general, and symmetry reduction methods are discussed briefly as a means of dealing with ‘large’ spin systems. 相似文献
37.
G. Glöckner 《Chromatographia》1987,23(7):517-524
Summary Prerequisite of quantitative evaluation in chromatography is equivalence of sample composition and detector signal. This includes
complete retention and proper elution of all sample constituents. In polymer HPLC, complete retention requires a poor starting
eluent, a sufficiently active column, and a low ratio of injection volume to column volume. On small pore columns, insufficient
retention caused the polymer to elute either in the interstitial volume (sample exclusion), together with the sample solvent,
or immediately after the solvent plug.Stat-copoly(styrene/ethyl methacrylate) samples are more difficultly retained thanstat-copoly(styrene/acrylonitrile) specimes. With the former copolymer it could be shown that incomplete retention did not cause
sample demixing. In order to gain complete retention, non-exclusion HPLC of polymers should be performed with columns whose
solvent volume is at least 50 times as large as the injection volume. This consequence is of practical importance in chromatographic
cross-fractionation where rather large volumes of SEC eluate are injected into the apparatus for gradient HPLC. 相似文献
38.
Several on-column sample preconcentration modes--large-volume sample stacking using the EOF pump (LVSEP), LVSEP with anion-selective exhaustive injection (LVSEP-ASEI) and field-amplified sample injection with sample matrix removal using the electroosmotic flow (EOF) pump (FAEP)--were used to analyze some nonsteroidal anti-inflammatory drugs (NSAIDs) by capillary electrophoresis, and then compared. Methanol was the background electrolyte solvent to suppress the EOF. The effect of the type and length of the solvent plug, and the sample injection time were investigated in FAEP to determine the conditions that provided the best response. LVSEP, LVSEP-ASEI, and FAEP improved the sensitivity of the peak area by 100-, 1200-, and 1800-fold, respectively. The methodology developed, in combination with solid-phase extraction (SPE), was applied to the analysis of water samples. 相似文献
39.
Th. Hankemeier P. C. Steketee J. J. Vreuls U. A. Th. Brinkman 《Journal of chromatography. A》1996,750(1-2):161-174
A fully automated at-line solid-phase extraction-gas chromatography procedure has been developed for the analysis of aqueous samples using the PrepStation. The sample extract is transferred from the sample preparation module to the gas chromatograph via an autosampler vial. With flame-ionization detection, limits of determination (S/N=10) of 0.05–0.13 μg/l were obtained for the analysis of HPLC-grade water when modifying the PrepStation by: (i) increasing the sample volume to 50 ml, (ii) increasing the injection volume up to 50 μl, and (iii) decreasing the desorption volume to 300 μl. The HP autosampler had to be modified to enable the automated “at-once” on-column injection of up to 50 μl of sample extract. The amount of packing material in the original cartridge had to be reduced to effect the decrease of the desorption volume. The total set-up did not require any further optimization after having set up the method once. The analytical characteristics of the organonitrogen and organophosphorus test analytes, i.e. recoveries (typically 75–105%), repeatability (2–8%) and linearity (0.09–3.0 μg/l) were satisfactory. The potential of the system was demonstrated by determining triazines and organophosphorus pesticides in river Rhine water at the 0.6 μg/l level using flame-ionization and mass-selective detection. No practical problems were observed during the analysis of more than 100 river water samples. 相似文献
40.
《Discrete Mathematics》2022,345(3):112721
This paper studies thresholds in random generalized Johnson graphs for containing large cycles, i.e. cycles of variable length growing with the size of the graph. Thresholds are obtained for different growth rates. 相似文献